U2N@Ih(7)-C80: fullerene cage encapsulating an unsymmetrical U(iv)NU(v) cluster
نویسندگان
چکیده
منابع مشابه
Switchable ErSc2N rotor within a C80 fullerene cage: an electron paramagnetic resonance and photoluminescence excitation study.
Motivated by the possibility of observing photoluminescence and electron paramagnetic resonance from the same species located within a fullerene molecule, we initiated an EPR study of Er3+ in ErSc2N@C80. Two orientations of the ErSc2N rotor within the C80 fullerene are observed in EPR, consistent with earlier studies using photoluminescence excitation (PLE) spectroscopy. For some crystal field ...
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A new Sc3(C2)(CN)@Ih-C80 metallofullerene encaging a scandium carbide/cyanide alloyed cluster was prepared and investigated. Sc3(C2)(CN)@Ih-C80 was synthesized by the arc-discharging method and isolated by HPLC. Its experimental (13)C NMR spectrum with two signals clearly confirms an icosahedral C80 cage, and theoretically calculated (13)C NMR peaks agree well with the experimental results. Fur...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2021
ISSN: 2041-6520,2041-6539
DOI: 10.1039/d0sc04677a